| Terminal stibinidene ligands. Generation of CpCp*Hf=Sb(dmp) and trapping reactions with PMe3 and 2-butyne. | |
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MedLine Citation:
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PMID: 17003889 Owner: NLM Status: PubMed-not-MEDLINE |
Abstract/OtherAbstract:
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Treating CpCp*HfMe(OTf) (1) with LiSbH(dmp) results in formation of CpCp*HfMe(SbHdmp), which undergoes alpha-abstraction to liberate methane and generate CpCp*Hf=Sb(dmp), which is thermally unstable but can be trapped with PMe(3) or 2-butyne to give CpCp*Hf(PMe(3))=Sb(dmp) (2) and CpCp*Hf[eta(2)-Sb,C:Sb(dmp)C(Me)=C(Me)] (3), respectively. |
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Authors:
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Rory Waterman; T Don Tilley |
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Publication Detail:
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Type: Journal Article Date: 2006-08-17 |
Journal Detail:
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Title: Chemical communications (Cambridge, England) Volume: - ISSN: 1359-7345 ISO Abbreviation: Chem. Commun. (Camb.) Publication Date: 2006 Oct |
Date Detail:
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Created Date: 2006-09-27 Completed Date: 2007-08-03 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9610838 Medline TA: Chem Commun (Camb) Country: England |
Other Details:
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Languages: eng Pagination: 4030-2 Citation Subset: - |
Affiliation:
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Department of Chemistry, University of California, Berkeley, California 94720-1460, USA. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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