Document Detail

Temperature and pressure-mediated structural transition of ZnS nanoparticles.
MedLine Citation:
PMID:  22849079     Owner:  NLM     Status:  In-Process    
We demonstrate that the structural transition of ZnS nanoparticles from sphalerite to wurtzite is influenced by high pressures and temperatures. Under the pressure of 1 GPa, the structural transition of ZnS nanoparticles commences at 250 degrees C, much lower than that 400-500 degrees C for ZnS nanoparticles under normal pressures. With the increase of the annealing temperature, the transition is enhanced then inhibited with a maximum transition fraction of 14% at 300 degrees C and disappears at 500 degrees C. At the annealing temperature of 300 degrees C, the structural transition of ZnS nanoparticles keeps almost invariable with the increase of the pressure from 0.6 GPa to 1 GPa. The mechanism for the phenomenon is discussed.
Xiaohong Li; Haitian Zhang; Defeng Guo; Cuizhuo Yang; Lei Xu; Yang Li; Yinan Li; Baoting Liu; Xiangyi Zhang
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  Journal of nanoscience and nanotechnology     Volume:  12     ISSN:  1533-4880     ISO Abbreviation:  J Nanosci Nanotechnol     Publication Date:  2012 Apr 
Date Detail:
Created Date:  2012-08-01     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101088195     Medline TA:  J Nanosci Nanotechnol     Country:  United States    
Other Details:
Languages:  eng     Pagination:  3154-8     Citation Subset:  IM    
College of Physics Science and Technology, Hebei University, 071002 Baoding, PR China.
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