Document Detail


Temperature and solvent-dependent morphological sol gel transformation: an in situ microscopic observation.
MedLine Citation:
PMID:  20095544     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
A thermoreversible self-assemble process from gel (fiber) to sol (vesicle) state in the system alkylamine-ethylene glycol is for the first time monitored by in situ polarized optical microscopy, XRD, (1)H NMR, SEM, SAXRD, FTIR and drop shape analysis. It is found that the solvent molecules are intercalated with alkylamine molecules to form the organogel and vesicle structures. A model based on structural transformation with respect to these alkylamine gelator-solvent assembles is therefore proposed.
Authors:
Yaqun Huang; Fenglin Liao; Weiran Zheng; Xiulan Liu; Xiaojun Wu; Xinlin Hong; Shik Chi Tsang
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Langmuir : the ACS journal of surfaces and colloids     Volume:  26     ISSN:  1520-5827     ISO Abbreviation:  Langmuir     Publication Date:  2010 Mar 
Date Detail:
Created Date:  2010-02-23     Completed Date:  2010-05-28     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9882736     Medline TA:  Langmuir     Country:  United States    
Other Details:
Languages:  eng     Pagination:  3106-14     Citation Subset:  -    
Affiliation:
College of Chemistry and Molecular Science, Wuhan University, PR China.
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