| Taming the germyliumylidene [CIGe:](+) and germathionium [CIGe[double bond, length as m-dash]S](+) ions by donor-acceptor stabilization using 1,8-bis(tributylphosphazenyl)naphthalene. | |
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MedLine Citation:
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PMID: 23147516 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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The novel chlorogermyliumylidene complex [ClGe:](+) ( = 1,8-bis(tri-n-butylphosphanzenyl)naphthalene) with a 'naked' Cl(-) as a counter anion was synthesized through reaction of with Cl(2)Ge: and fully characterized. Its reaction with elemental sulfur afforded the first germathionium [ClGe[double bond, length as m-dash]S](+) cation containing species. The latter has also been fully characterized, including single-crystal X-ray diffraction analysis. |
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Authors:
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Yun Xiong; Shenglai Yao; Shigeyoshi Inoue; Andreas Berkefeld; Matthias Driess |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-11-12 |
Journal Detail:
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Title: Chemical communications (Cambridge, England) Volume: - ISSN: 1364-548X ISO Abbreviation: Chem. Commun. (Camb.) Publication Date: 2012 Nov |
Date Detail:
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Created Date: 2012-11-13 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9610838 Medline TA: Chem Commun (Camb) Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Technische Universität Berlin, Department of Chemistry, Metalorganics and Inorganic Materials, Sekr. C2, Strasse des 17. Juni 135, D-10623 Berlin, Germany. matthias.driess@tu-berlin.de http://www.driess.tu-berlin.de. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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