Document Detail

Taming the germyliumylidene [CIGe:](+) and germathionium [CIGe[double bond, length as m-dash]S](+) ions by donor-acceptor stabilization using 1,8-bis(tributylphosphazenyl)naphthalene.
MedLine Citation:
PMID:  23147516     Owner:  NLM     Status:  Publisher    
The novel chlorogermyliumylidene complex [ClGe:](+) ( = 1,8-bis(tri-n-butylphosphanzenyl)naphthalene) with a 'naked' Cl(-) as a counter anion was synthesized through reaction of with Cl(2)Ge: and fully characterized. Its reaction with elemental sulfur afforded the first germathionium [ClGe[double bond, length as m-dash]S](+) cation containing species. The latter has also been fully characterized, including single-crystal X-ray diffraction analysis.
Yun Xiong; Shenglai Yao; Shigeyoshi Inoue; Andreas Berkefeld; Matthias Driess
Related Documents :
24302256 - Luminescent alkynyl-gold(i) coumarin derivatives and their biological activity.
24448646 - Control of the anisotropic shape of cobalt nanorods in the liquid phase: from experimen...
24856086 - Enrichment of chemical libraries docked to protein conformational ensembles and applica...
25007206 - Surfactant-directed atomic to mesoscale alignment: metal nano-crystals encased individu...
2906656 - The use of an animal-baited net trap for collecting mosquitoes during western equine en...
9057826 - Effect of complexes of adp and phosphate analogs on the conformation of the cys707-cys6...
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-11-12
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2012 Nov 
Date Detail:
Created Date:  2012-11-13     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Technische Universität Berlin, Department of Chemistry, Metalorganics and Inorganic Materials, Sekr. C2, Strasse des 17. Juni 135, D-10623 Berlin, Germany.
Export Citation:
APA/MLA Format     Download EndNote     Download BibTex
MeSH Terms

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine

Previous Document:  Exogenous Glutamate Modulates Porcine Retinal Development in vitro.
Next Document:  Generation of hypoallergenic neoglycoconjugates for dendritic cell targeted vaccination: a novel too...