Document Detail


Taming the germyliumylidene [CIGe:](+) and germathionium [CIGe[double bond, length as m-dash]S](+) ions by donor-acceptor stabilization using 1,8-bis(tributylphosphazenyl)naphthalene.
MedLine Citation:
PMID:  23147516     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The novel chlorogermyliumylidene complex [ClGe:](+) ( = 1,8-bis(tri-n-butylphosphanzenyl)naphthalene) with a 'naked' Cl(-) as a counter anion was synthesized through reaction of with Cl(2)Ge: and fully characterized. Its reaction with elemental sulfur afforded the first germathionium [ClGe[double bond, length as m-dash]S](+) cation containing species. The latter has also been fully characterized, including single-crystal X-ray diffraction analysis.
Authors:
Yun Xiong; Shenglai Yao; Shigeyoshi Inoue; Andreas Berkefeld; Matthias Driess
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-11-12
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2012 Nov 
Date Detail:
Created Date:  2012-11-13     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Technische Universität Berlin, Department of Chemistry, Metalorganics and Inorganic Materials, Sekr. C2, Strasse des 17. Juni 135, D-10623 Berlin, Germany. matthias.driess@tu-berlin.de http://www.driess.tu-berlin.de.
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