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THz rotational spectrum of H(2)F(+).
MedLine Citation:
PMID:  23039600     Owner:  NLM     Status:  In-Data-Review    
Abstract/OtherAbstract:
In view of recent tremendous advance in astronomical observations in the submillimeter to THz region brought by the Herschel space craft, laboratory high-resolution spectroscopic investigations in that frequency region into unstable molecules, in particular, light hydride ions, are urgently needed. As a part of such endeavor, rotational transitions of H(2)F(+) were observed in the THz-region by using a tunable far-infrared spectrometer. These newly detected lines together with the submillimeter-wave lines obtained previously and the combination differences derived from infrared vibration-rotation lines were subject to a least-squares analysis that yielded a set of molecular constants with much better accuracy. The measured and predicted THz transition frequencies should prove to be a useful probe into detection of interstellar H(2)F(+).
Authors:
T Amano; F Matsushima; T Shiraishi; C Shinozuka; R Fujimori; K Kawaguchi
Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  The Journal of chemical physics     Volume:  137     ISSN:  1089-7690     ISO Abbreviation:  J Chem Phys     Publication Date:  2012 Oct 
Date Detail:
Created Date:  2012-10-08     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0375360     Medline TA:  J Chem Phys     Country:  United States    
Other Details:
Languages:  eng     Pagination:  134308     Citation Subset:  IM    
Affiliation:
Department of Chemistry and Department of Physics and Astronomy, The University of Waterloo, Waterloo, Ontario N2L 3G1, Canada.
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