Document Detail


Synthetic Precursors for TCNQF(4)(2-) Compounds: Synthesis, Characterization, and Electrochemical Studies of (Pr(4)N)(2)TCNQF(4) and Li(2)TCNQF(4).
MedLine Citation:
PMID:  23153174     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Careful control of the reaction stoichiometry and conditions enables the synthesis of both LiTCNQF(4) and Li(2)TCNQF(4) to be achieved. Reaction of LiI with TCNQF(4), in a 4:1 molar ratio, in boiling acetonitrile yields Li(2)TCNQF(4). However, deviation from this ratio or the reaction temperature gives either LiTCNQF(4) or a mixture of Li(2)TCNQF(4) and LiTCNQF(4). This is the first report of the large-scale chemical synthesis of Li(2)TCNQF(4). Attempts to prepare a single crystal of Li(2)TCNQF(4) have been unsuccessful, although air-stable (Pr(4)N)(2)TCNQF(4) was obtained by mixing Pr(4)NBr with Li(2)TCNQF(4) in aqueous solution. Pr(4)NTCNQF(4) was also obtained by reaction of LiTCNQF(4) with Pr(4)NBr in water. Li(2)TCNQF(4), (Pr(4)N)(2)TCNQF(4), and Pr(4)NTCNQF(4) have been characterized by UV-vis, FT-IR, Raman, and NMR spectroscopy, high resolution electrospray ionization mass spectrometry, and electrochemistry. The structures of single crystals of (Pr(4)N)(2)TCNQF(4) and Pr(4)NTCNQF(4) have been determined by X-ray crystallography. These TCNQF(4)(2-) salts will provide useful precursors for the synthesis of derivatives of the dianions.
Authors:
Jinzhen Lu; Thanh Hai Le; Daouda A K Traore; Matthew Wilce; Alan M Bond; Lisandra L Martin
Related Documents :
17808284 - X-ray-induced bulk photovoltaic effect in insulators.
23305964 - Synthesis, characterization, and biological evaluation of new tetrazole-based platinum(...
21581424 - (e)-ethyl 3-(4-fluoro-anilino)-2-(4-methoxy-phen-yl)acrylate.
19754204 - Asymmetries in transition metal xps spectra: metal nanoparticle structure, and interact...
8348544 - Isolation and characterisation of hemicelluloses from sunflower hulls.
15299484 - Crystallization and preliminary x-ray studies on the mannose-specific lectin from amary...
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-11-15
Journal Detail:
Title:  The Journal of organic chemistry     Volume:  -     ISSN:  1520-6904     ISO Abbreviation:  J. Org. Chem.     Publication Date:  2012 Nov 
Date Detail:
Created Date:  2012-11-16     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  2985193R     Medline TA:  J Org Chem     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
School of Chemistry, Monash University , Wellington Road, Clayton, Victoria 3800, Australia.
Export Citation:
APA/MLA Format     Download EndNote     Download BibTex
MeSH Terms
Descriptor/Qualifier:

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


Previous Document:  Antioxidant activity and cytotoxicity of Cyrtosperma johnstonii extracts on drug sensitive and resis...
Next Document:  A randomised comparison of InnoScope and Macintosh laryngoscope in simulated difficult tracheal intu...