Document Detail

Synthetic control of composition and crystallite size of silver hollandite, Ag(x)Mn8O16: impact on electrochemistry.
MedLine Citation:
PMID:  23046050     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Synthetic control of the silver content in silver hollandite, Ag(x)Mn(8)O(16), where the silver content ranges from 1.0 ≤ x ≤ 1.8 is demonstrated. This level of compositional control was enabled by the development of a lower temperature reflux based synthesis compared to the more commonly reported hydrothermal approach. Notably, the synthetic variance of the silver content was accompanied by a concomitant variance in crystallite size as well as surface area and particle size. To verify the retention of the hollandite structure, the first Rietveld analysis of silver hollandite was conducted on samples of varying composition. The impacts of silver content, crystallite size, surface area, and particle size on electrochemical reversibility were examined under cyclic voltammetry and battery testing.
Kenneth J Takeuchi; Shali Z Yau; Melissa C Menard; Amy C Marschilok; Esther S Takeuchi
Publication Detail:
Type:  Journal Article; Research Support, N.I.H., Extramural; Research Support, Non-U.S. Gov't; Research Support, U.S. Gov't, Non-P.H.S.     Date:  2012-10-09
Journal Detail:
Title:  ACS applied materials & interfaces     Volume:  4     ISSN:  1944-8252     ISO Abbreviation:  ACS Appl Mater Interfaces     Publication Date:  2012 Oct 
Date Detail:
Created Date:  2012-10-24     Completed Date:  2013-03-18     Revised Date:  2013-10-28    
Medline Journal Info:
Nlm Unique ID:  101504991     Medline TA:  ACS Appl Mater Interfaces     Country:  United States    
Other Details:
Languages:  eng     Pagination:  5547-54     Citation Subset:  -    
Department of Chemistry, Stony Brook University (SUNY), Stony Brook, New York 11794, USA.
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