Document Detail


Synthesis of thienyl analogues of PCBM and investigation of morphology of mixtures in P3HT.
MedLine Citation:
PMID:  18941618     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
Novel [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) analogues containing benzo[b]thiophene (3a, 3b) and thieno[3,2-b]thiophene (3c, 3d) were synthesized and characterized. The morphology of the thin films prepared from the mixtures of these methanofullerenes with regioregular poly(3-hexylthiophene) (P3HT) was investigated by AFM measurement and UV-Vis absorption spectroscopy. A solubility test of these methanofullerenes was performed by using dichloromethane as a solvent. es-TThCBM (3d) exhibited 1.4 times greater solubility in dichloromethane than PCBM.
Authors:
Fukashi Matsumoto; Kazuyuki Moriwaki; Yuko Takao; Toshinobu Ohno
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Publication Detail:
Type:  Journal Article     Date:  2008-09-29
Journal Detail:
Title:  Beilstein journal of organic chemistry     Volume:  4     ISSN:  1860-5397     ISO Abbreviation:  Beilstein J Org Chem     Publication Date:  2008  
Date Detail:
Created Date:  2008-10-22     Completed Date:  2010-05-20     Revised Date:  2013-05-23    
Medline Journal Info:
Nlm Unique ID:  101250746     Medline TA:  Beilstein J Org Chem     Country:  Germany    
Other Details:
Languages:  eng     Pagination:  33     Citation Subset:  -    
Affiliation:
Osaka Municipal Technical Research Institute, 1-6-50 Morinomiya, Joto-ku, Osaka 536-8553, Japan. matumoto@omtri.city.osaka.jp
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