Document Detail


Synthesis and structure of a hydrogenated zinc hemiporphyrazine.
MedLine Citation:
PMID:  23149500     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Palladium-catalyzed hydrogenation of an octahedral zinc trans-ditriflate hemiporphyrazine "HpH(2)Zn(OTf)(2)" furnishes a new macrocycle "HpH(6)Zn(OTf)(2)". This reaction is fully reversible upon heating in nitrobenzene, and the conversion is easily monitored by changes in color and fluorescence properties. The reversible cycling between these molecules may find future applications in hemiporphyrazine-based catalysts and/or hydrogen storage devices.
Authors:
Sabrina M Huber; Guillaume Mata; Anthony Linden; Nathan W Luedtke
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-11-13
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2012 Nov 
Date Detail:
Created Date:  2012-11-14     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Institute of Organic Chemistry, University of Zürich, Winterthurerstrasse 190, CH-8057 Zürich, Switzerland. luedtke@oci.uzh.ch.
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