Document Detail


Synthesis, structure and π-delocalization of a phosphaalkenyl based neutral PNP-pincer.
MedLine Citation:
PMID:  21966023     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Preparation, characterization and structural properties of a novel bis-phosphaalkenyl based PNP-pincer are reported. In this pincer the π-system is delocalized over all three donor sites, which was demonstrated with DFT calculations, UV-Vis measurements and structural findings. As a consequence of this extended delocalization the π-system reveals near coplanarity which is evident from the first crystal structure for an uncomplexed bisphosphaalkenyl PNP-pincer.
Authors:
Andreas Orthaber; Ferdinand Belaj; Rudolf Pietschnig
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Publication Detail:
Type:  JOURNAL ARTICLE    
Journal Detail:
Title:  Inorganica chimica acta     Volume:  374     ISSN:  0020-1693     ISO Abbreviation:  -     Publication Date:  2011 Aug 
Date Detail:
Created Date:  2011-10-3     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9875013     Medline TA:  Inorganica Chim Acta     Country:  -    
Other Details:
Languages:  ENG     Pagination:  211-215     Citation Subset:  -    
Affiliation:
Karl-Franzens-University, Department of Chemistry, Schuberststraße 1, A-8010 Graz, Austria.
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