Document Detail


Synthesis and spectroscopic studies of a new 1,8-naphthalimide dyad as detector for metal cations and protons.
MedLine Citation:
PMID:  20399137     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
A new dyad containing two 1,8-naphthalimides has been synthesized. N,N-Dimetylaminoethylamino group has been used as substituent at C-4 position of the 1,8-naphthalimide chromophore structure. The photophysical characteristics of the dyad have been investigated in organic solvents with different polarity. In acetonitrile solution the newly synthesized dyad enhance its fluorescent intensity in the presence of metal cations (Ni(2+), Co(2+), Cu(2+), Pb(2)(+), Zn(2+), Fe(3+)) and protons due to quenching of photoinduced electron transfer.
Authors:
Desislava Staneva; Mark McKena; Paula Bosch; Ivo Grabchev
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Publication Detail:
Type:  Journal Article     Date:  2010-03-19
Journal Detail:
Title:  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy     Volume:  76     ISSN:  1873-3557     ISO Abbreviation:  Spectrochim Acta A Mol Biomol Spectrosc     Publication Date:  2010 Jul 
Date Detail:
Created Date:  2010-05-05     Completed Date:  2010-08-06     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9602533     Medline TA:  Spectrochim Acta A Mol Biomol Spectrosc     Country:  England    
Other Details:
Languages:  eng     Pagination:  150-4     Citation Subset:  IM    
Copyright Information:
Copyright 2010 Elsevier B.V. All rights reserved.
Affiliation:
Institute of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences, 1113 Sofia, Bulgaria.
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MeSH Terms
Descriptor/Qualifier:
Cations / analysis*
Metals / analysis*
Naphthalimides / chemical synthesis,  chemistry*
Photochemistry
Protons
Spectrometry, Fluorescence / methods*
Chemical
Reg. No./Substance:
0/Cations; 0/Metals; 0/Naphthalimides; 0/Protons

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