Document Detail


Synthesis of a ruthenium bis(diisopropylamino(isocyano)borane) complex from the activation of an amino(cyano)borane.
MedLine Citation:
PMID:  23196912     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The reactivity of the amino(cyano)borane (i)Pr(2)NBH(CN) () towards [RuH(2)(η(2)-H(2))(2)(PCy(3))(2)] () was investigated. Our study reveals that the formation of the bis(isocyanoborane) ruthenium complex [RuH(CN)(CN-BHN(i)Pr(2))(2)(PCy(3))(2)] () occurs via the intermediacy of the bis(σ-B-H) ruthenium complex [RuH(CN)(H(2)BN(i)Pr(2))(PCy(3))(2)] (). This transformation involves BCN linkage isomerisation in . The diisopropylaminoborane ligand in can be displaced to ultimately produce the bis(σ-borane) complex [RuH(2)(η(2):η(2)-H(2)BN(i)Pr(2))(PCy(3))(2)] () as a by-product.
Authors:
Maximilian Joost; Gilles Alcaraz; Laure Vendier; Amalia Poblador-Bahamonde; Eric Clot; Sylviane Sabo-Etienne
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-11-30
Journal Detail:
Title:  Dalton transactions (Cambridge, England : 2003)     Volume:  -     ISSN:  1477-9234     ISO Abbreviation:  Dalton Trans     Publication Date:  2012 Nov 
Date Detail:
Created Date:  2012-11-30     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101176026     Medline TA:  Dalton Trans     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
CNRS, LCC (Laboratoire de Chimie de Coordination), BP44099, 205 route de Narbonne, F-31077 Toulouse cedex 4, France. sylviane.sabo@lcc-toulouse.fr gilles.alcaraz@lcc-toulouse.fr.
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