| Synthesis and reactions of 2,2-[60]fullerenoalkanoyl chlorides. | |
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MedLine Citation:
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PMID: 16468817 Owner: NLM Status: PubMed-not-MEDLINE |
Abstract/OtherAbstract:
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2,2-[60]Fullerenoalkanoyl chlorides (1a-d) were easily and securely prepared from the corresponding 2,2-[60]fullerenoalkanoic acids (2a-d) by the reaction with thionyl chloride in an unusual mixed solvent, CH2Cl2/dioxane. The characterization of 1a-d by 1H and 13C NMR, FT-IR, and MALDI-TOF-MASS was conducted for the first time. The 2,2-[60]fullerenoalkanoyl chlorides thus obtained were readily converted to the corresponding amides and esters in moderate to excellent yields by the condensation with amines and alcohols, respectively. Upon applying the condensation, [60]fullerene-biomolecule hybrids were easily prepared. |
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Authors:
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Tomoyuki Tada; Yasuhiro Ishida; Kazuhiko Saigo |
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Publication Detail:
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Type: Journal Article |
Journal Detail:
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Title: The Journal of organic chemistry Volume: 71 ISSN: 0022-3263 ISO Abbreviation: J. Org. Chem. Publication Date: 2006 Feb |
Date Detail:
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Created Date: 2006-02-10 Completed Date: 2006-12-08 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 2985193R Medline TA: J Org Chem Country: United States |
Other Details:
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Languages: eng Pagination: 1633-9 Citation Subset: - |
Affiliation:
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Department of Chemistry and Biotechnology, Graduate School of Engineering, University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656, Japan. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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