Document Detail


Synthesis of hydroxytyrosol, 2-hydroxyphenylacetic acid, and 3-hydroxyphenylacetic acid by differential conversion of tyrosol isomers using Serratia marcescens strain.
MedLine Citation:
PMID:  16076144     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
We investigated to develop an effective procedure to produce the potentially high-added-value phenolic compounds through bioconversion of tyrosol isomers. A soil bacterium, designated Serratia marcescens strain, was isolated on the basis of its ability to grow on p-tyrosol (4-hydroxyphenylethanol) as a sole source of carbon and energy. During growth on p-tyrosol, Ser. marcescens strain was capable of promoting the formation of hydroxytyrosol. To achieve maximal hydroxytyrosol yield, the growth state of the culture utilized for p-tyrosol conversion as well as the amount of p-tyrosol that was treated were optimized. The optimal yield of hydroxytyrosol (80%) was obtained by Ser. marcescens growing cells after a 7-h incubation using 2 g/L of p-tyrosol added at the end of the exponential phase to a culture pregrown on 1 g/L of p-tyrosol. Furthermore, the substrate specificity of the developed biosynthesis was investigated using m-tyrosol (3-hydroxyphenylethanol) and o-tyrosol (2-hydroxyphenylethanol) as substrates. Ser. marcescens strain transformed completely m-tyrosol and o-tyrosol into 3-hydroxyphenylacetic acid and 2-hydroxyphenylacetic acid, respectively, via the oxidation of the side chain carbon of the treated substrates. This proposed procedure is an alternative approach to obtain hydroxytyrosol, 2-hydroxyphenylacetic acid, and 3-hydroxyphenylacetic acid in an environmentally friendly way which could encourage their use as alternatives in the search for replacement of synthetic food additives.
Authors:
Noureddine Allouche; Sami Sayadi
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  Journal of agricultural and food chemistry     Volume:  53     ISSN:  0021-8561     ISO Abbreviation:  J. Agric. Food Chem.     Publication Date:  2005 Aug 
Date Detail:
Created Date:  2005-08-03     Completed Date:  2005-09-19     Revised Date:  2006-11-15    
Medline Journal Info:
Nlm Unique ID:  0374755     Medline TA:  J Agric Food Chem     Country:  United States    
Other Details:
Languages:  eng     Pagination:  6525-30     Citation Subset:  IM    
Affiliation:
Laboratoire des Bio-Procédés, Centre de Biotechnologie de Sfax B.P K. 3038, Sfax, Tunisia.
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MeSH Terms
Descriptor/Qualifier:
Kinetics
Phenylacetates / metabolism*
Phenylethyl Alcohol / analogs & derivatives*,  metabolism
Serratia marcescens / metabolism*
Soil Microbiology
Chemical
Reg. No./Substance:
0/Phenylacetates; 10597-60-1/3,4-dihydroxyphenylethanol; 501-94-0/4-hydroxyphenylethanol; 60-12-8/Phenylethyl Alcohol; 614-75-5/2-hydroxyphenylacetic acid; 621-37-4/3-hydroxyphenylacetic acid

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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