Document Detail


Synthesis of highly enantiomerically enriched planar chiral ruthenium complexes via Pd-catalysed asymmetric hydrogenolysis.
MedLine Citation:
PMID:  19707628     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
Key elements in this communication are a very efficient microwave synthesis of [RuCp(naphthalene)][PF(6)], the precursor of [RuCp(CH(3)CN)(3)][PF(6)], and a Pd-catalysed asymmetric hydrogenolysis to afford planar chiral ruthenium complexes with high levels of enantioselectivity using a bulky chiral phosphoramidite ligand.
Authors:
Audrey Mercier; Wee Chuan Yeo; Jingyu Chou; Piyali Datta Chaudhuri; G??rald Bernardinelli; E Peter K??ndig
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Publication Detail:
Type:  Journal Article     Date:  2009-08-05
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2009 Sep 
Date Detail:
Created Date:  2009-08-26     Completed Date:  2009-12-28     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  England    
Other Details:
Languages:  eng     Pagination:  5227-9     Citation Subset:  -    
Affiliation:
Department of Organic Chemistry, University of Geneva, Quai Ernest Ansermet 30, 1211 Geneva 4, Switzerland.
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