| Synthesis of gamma,delta-unsaturated glycolic acids via sequenced brook and Ireland--claisen rearrangements. | |
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MedLine Citation:
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PMID: 20143793 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
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Organozinc, -magnesium, and -lithium nucleophiles initiate a Brook/Ireland-Claisen rearrangement sequence of allylic silyl glyoxylates resulting in the formation of gamma,delta-unsaturated alpha-silyloxy acids. |
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Authors:
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Daniel C Schmitt; Jeffrey S Johnson |
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Publication Detail:
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Type: Journal Article; Research Support, N.I.H., Extramural; Research Support, Non-U.S. Gov't |
Journal Detail:
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Title: Organic letters Volume: 12 ISSN: 1523-7052 ISO Abbreviation: Org. Lett. Publication Date: 2010 Mar |
Date Detail:
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Created Date: 2010-03-01 Completed Date: 2010-05-20 Revised Date: 2011-07-26 |
Medline Journal Info:
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Nlm Unique ID: 100890393 Medline TA: Org Lett Country: United States |
Other Details:
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Languages: eng Pagination: 944-7 Citation Subset: IM |
Affiliation:
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Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599-3290, USA. |
Export Citation:
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APA/MLA Format Download EndNote Download BibTex |
| MeSH Terms | |
Descriptor/Qualifier:
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Dimerization Glycolates / chemical synthesis*, chemistry* Glyoxylates / chemistry |
| Grant Support | |
ID/Acronym/Agency:
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GM084927/GM/NIGMS NIH HHS; R01 GM084927-01A1/GM/NIGMS NIH HHS |
| Chemical | |
Reg. No./Substance:
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0/Glycolates; 0/Glyoxylates; 298-12-4/glyoxylic acid; 79-14-1/glycolic acid |
| Comments/Corrections | |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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