Document Detail


Synthesis of the epimer of pericosine B from (-)-quinic Acid.
MedLine Citation:
PMID:  15340204     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Synthesis of the epimer of pericosine B from (-)-quinic acid was achieved. This synthesis involves some regioselective and stereoselective processes. The desired product showed lower cytotoxic activity in comparison with natural pericosine B against the P388 leukemia cell line. The result implies that the stereocenter of C-6 in natural pericosine B plays an important role in this activity.
Authors:
Yoshihide Usami; Chikage Hatsuno; Hiroe Yamamoto; Manabu Tanabe; Atsushi Numata
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  Chemical & pharmaceutical bulletin     Volume:  52     ISSN:  0009-2363     ISO Abbreviation:  Chem. Pharm. Bull.     Publication Date:  2004 Sep 
Date Detail:
Created Date:  2004-09-01     Completed Date:  2005-02-23     Revised Date:  2006-11-15    
Medline Journal Info:
Nlm Unique ID:  0377775     Medline TA:  Chem Pharm Bull (Tokyo)     Country:  Japan    
Other Details:
Languages:  eng     Pagination:  1130-3     Citation Subset:  IM    
Affiliation:
Osaka University of Pharmaceutical Sciences, Takatsuki, Osaka 569-1094, Japan. usami@gly.oups.ac.jp
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MeSH Terms
Descriptor/Qualifier:
Animals
Antineoplastic Agents / chemical synthesis*,  chemistry
Cell Line, Tumor
Mice
Molecular Conformation
Molecular Structure
Quinic Acid / chemistry*
Shikimic Acid / analogs & derivatives*,  chemical synthesis*,  chemistry,  pharmacology
Stereoisomerism
Chemical
Reg. No./Substance:
0/Antineoplastic Agents; 0/pericosine B; 138-59-0/Shikimic Acid; 77-95-2/Quinic Acid
Comments/Corrections
Erratum In:
Chem Pharm Bull (Tokyo). 2005 Jun;53(6):721
Chem Pharm Bull (Tokyo). 2004 Dec;52(12):1511

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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