Document Detail


Synthesis and characterization of ultra-fine Y2O3:Eu3+ nanophosphors for luminescent security ink applications.
MedLine Citation:
PMID:  20051611     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
We report a simple method for the synthesis of ultra-fine Eu(3+)-doped yttria (Y(2)O(3)) nanophosphors with an average diameter of approximately 5 nm for development of a transparent colloid that could be used as a luminescent security ink. This has been achieved by suitably substituting Eu(3+) ions at the favorable C(2) symmetry sites of Y(3+) ions and quantum mechanically confining the growth of the nanophosphor using a novel acid-catalyzed sol-gel technique. This is one of the few reports that depict the development of a transparent aqueous-stable Y(2)O(3):Eu(3+) colloidal solution for strategic applications related to security codes. High resolution transmission electron microscopy images showed excellent lattice fringes that in turn support the presence of better crystal quality and enhanced photoluminescence (PL) emission from the Y(1.9)O(3)Eu(0.1)(3+) nanophosphor system. Time resolved emission spectroscopy measurement indicated a PL decay time in the range of a few milliseconds, suitable for making luminescent security ink and other advanced applications in optoelectronic devices and bio-labeling.
Authors:
Bipin Kumar Gupta; D Haranath; Shikha Saini; V N Singh; V Shanker
Publication Detail:
Type:  Journal Article     Date:  2010-01-06
Journal Detail:
Title:  Nanotechnology     Volume:  21     ISSN:  1361-6528     ISO Abbreviation:  Nanotechnology     Publication Date:  2010 Feb 
Date Detail:
Created Date:  2010-01-06     Completed Date:  2010-03-22     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101241272     Medline TA:  Nanotechnology     Country:  England    
Other Details:
Languages:  eng     Pagination:  055607     Citation Subset:  IM    
Affiliation:
National Physical Laboratory, Council of Scientific and Industrial Research, Dr K S Krishnan Road, New Delhi-110 012, India. bipinbhu@yahoo.com
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MeSH Terms
Descriptor/Qualifier:
Europium / chemistry*
Ink*
Luminescent Agents / chemistry*
Metal Nanoparticles / chemistry*
Microscopy, Electron, Scanning
Microscopy, Electron, Transmission
Security Measures
Temperature
X-Ray Diffraction
Yttrium / chemistry*
Chemical
Reg. No./Substance:
0/Luminescent Agents; 1314-36-9/yttria; 7440-53-1/Europium; 7440-65-5/Yttrium

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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