| Synthesis and characterization of toluene-3,4-dithiolatoantimony(III) derivatives with some oxygen and/or sulphur donor ligands. | |
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MedLine Citation:
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PMID: 19560395 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
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Replacement reactions of toluene-3,4-dithiolatoantimony(III) chloride with oxygen and/or sulphur donor ligands like benzoic acid, thiobenzoic acid, thioacetic acid, phenol, thiophenol, sodium salicylate and thio glycolic acid in 1:1 molar ratio as well as disodium oxalate in 2:1 molar ratio in refluxing anhydrous benzene yielded toluene-3,4-dithiolatoantimony(III) mono oxo and/or thio carboxylic or phenolic derivatives of the general formula {R=OOCC(6)H(5), SOCC(6)H(5), SOCCH(3), OC(6)H(5), SC(6)H(5), OOCC(6)H(4)(OH) and SCH(2)COOH} and These newly synthesized derivatives are yellow and brown solids/liquids and are soluble in common organic solvents like benzene, chloroform, dichloromethane, etc. These derivatives have been characterized by melting point determination, molecular weight determination, elemental analysis (C, H, S and Sb), spectral {UV, IR and NMR ((1)H and (13)C)} and thermal (TGA, DTA and DSC) studies. |
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Authors:
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H P S Chauhan; Sumit Bhatiya; Abhilasha Bakshi |
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Publication Detail:
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Type: Journal Article; Research Support, Non-U.S. Gov't Date: 2009-05-20 |
Journal Detail:
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Title: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy Volume: 74 ISSN: 1873-3557 ISO Abbreviation: Spectrochim Acta A Mol Biomol Spectrosc Publication Date: 2009 Sep |
Date Detail:
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Created Date: 2009-08-24 Completed Date: 2009-11-30 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9602533 Medline TA: Spectrochim Acta A Mol Biomol Spectrosc Country: England |
Other Details:
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Languages: eng Pagination: 67-73 Citation Subset: IM |
Affiliation:
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School of Chemical Sciences, Devi Ahilya University, Takshashila Campus, Khandwa Road, Indore 452001, India. hpsc@rediffmail.com |
Export Citation:
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| MeSH Terms | |
Descriptor/Qualifier:
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Antimony
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chemistry* Ligands Magnetic Resonance Spectroscopy Models, Biological Oxygen / chemistry* Spectrophotometry, Infrared Spectrophotometry, Ultraviolet Sulfhydryl Compounds / chemical synthesis*, chemistry Sulfur / chemistry* Thermodynamics Toluene / analogs & derivatives, chemistry |
| Chemical | |
Reg. No./Substance:
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0/Ligands; 0/Sulfhydryl Compounds; 108-88-3/Toluene; 496-74-2/dithiol; 507-09-5/thioacetic acid; 7440-36-0/Antimony; 7704-34-9/Sulfur; 7782-44-7/Oxygen |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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