Document Detail

Synthesis and characterization of compounds with the Al-O-X (X = Si, P, C) structural motif.
MedLine Citation:
PMID:  23018666     Owner:  NLM     Status:  Publisher    
The reactions of LAlH(2) (L = HC(CMeNAr)(2), Ar = 2,6-iPr(2)C(6)H(3)) () with diphenylsilanediol, phenylphosphonic acid, diphenylphosphinic acid, and pyrocatechol afford compounds with the Al-O-X (X = Si, P, C) motif of composition [LAl(μ-O)](2)Si(Ph)(2) (), [LAl(μ-O)](2)PO(Ph) (), LAl[OPO(Ph)(2)](2) (), and LAl(μ-O)(2)(o-C(6)H(4)) (), respectively. Compound contains the Al-O-Si-O-Al heterotrimetallic dioxide chain. Compound features an Al(μ-O)](2)P four-membered ring, while compound exhibits a P-O-Al-O-P chain structure. Compound contains the benzo-aluminum-dioxide organic-inorganic hybrid five-membered ring. Complexes , , , and were characterized by NMR, elementary analysis, and single-crystal X-ray diffraction.
Pengfei Hao; Zhi Yang; Xiaoli Ma; Xiujuan Wang; Zhihong Liu; Herbert W Roesky; Kening Sun; Jiarong Li; Mingdong Zhong
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-9-28
Journal Detail:
Title:  Dalton transactions (Cambridge, England : 2003)     Volume:  -     ISSN:  1477-9234     ISO Abbreviation:  Dalton Trans     Publication Date:  2012 Sep 
Date Detail:
Created Date:  2012-9-28     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101176026     Medline TA:  Dalton Trans     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
School of Chemical Engineering and Environment, Beijing Institute of Technology, 100081 Beijing, China.
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