Document Detail


Synthesis of Pd-coated FeCo@Fe/C core-shell nanoparticles: microwave-induced 'top-down' nanostructuring and decoration.
MedLine Citation:
PMID:  23381686     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
We report a novel microwave-induced fast and efficient synthesis of sub-10 nm sized palladium-decorated FeCo@Fe core-shell nanoparticles (ca. 3-7 nm) from a large-sized FeCo@Fe (0.21-1.5 μm) precursor, suggesting 'top-down' nanosizing. The high electrochemical surface area, tolerance to methanol during oxygen reduction reaction, and the excellent stability of FeCo@Fe@Pd in alkaline electrolytes indicate that this nanomaterial may find future applications in Pd-based catalysis and/or alkaline fuel cells.
Authors:
Omobosede O Fashedemi; Basil Julies; Kenneth I Ozoemena
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-2-5
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2013 Feb 
Date Detail:
Created Date:  2013-2-5     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Department of Chemistry, University of Pretoria, Pretoria 0002, South Africa.
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