| Synthesis of Palladium Nanoparticles Supported on Mesoporous N-doped Carbon and Their Catalytic Ability for Biofuel Upgrade. | |
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MedLine Citation:
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PMID: 23030399 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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We report here a catalyst made of Pd nanoparticles supported on a mesoporous N-doped carbon, Pd@CN0.132, which was shown to be highly active and promoted the biomass refining. Using task-specific ionic liquid (3-methyl-1-butylpyridine dicyanamide) as precursor and silica nanoparticles as hard template, high nitrogen (12 wt%) con-tent, mesoporous carbon material was yielded and this N-doped carbon showed high active in stabilizing Pd nanopar-ticles. It is demonstrated that the resulting Pd@CN0.132 cata-lyst show very high catalytic activity in hydrodeoxygenation of vanillin (a typical model compound of lignin) in low H2 pressure under mild condition in aqueous media. Excellent catalytic results (100% conversion of vanillin and 100% selec-tivity of 2-methoxy-4-methyl phenol) were achieved and no loss of catalytic activity was observed after 6 recycles. |
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Authors:
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Xuan Xu; Yi Li; Yutong Gong; Pengfei Zhang; Haoran Li; Yong Wang |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-10-3 |
Journal Detail:
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Title: Journal of the American Chemical Society Volume: - ISSN: 1520-5126 ISO Abbreviation: J. Am. Chem. Soc. Publication Date: 2012 Oct |
Date Detail:
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Created Date: 2012-10-3 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 7503056 Medline TA: J Am Chem Soc Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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