| Synthesis of a High-Valent, Four-Coordinate Manganese Cubane Cluster with a Pendant Mn Atom: Photosystem II-Inspired Manganese-Nitrogen Clusters. | |
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MedLine Citation:
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PMID: 22439626 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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High-valent, four-coordinate manganese imido- and nitrido-bridged heterodicubane clusters have been prepared and characterized by single-crystal X-ray diffraction and spectroscopic techniques. The title compound, a corner-nitride-fused dicubane with the chemical formula [Mn(5)Li(3)(μ(6)-N)(N)(μ(3)-N(t)Bu)(6)(μ-N(t)Bu)(3)(N(t)Bu)] (1), has been prepared as an adduct with a nearly isostructural tetramanganese cluster with one Mn atom replaced by Li. An important feature of the reported chemistry is the formation of nitride from tert-butylamide, indicative of N-C bond cleavage facilitated by manganese. |
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Authors:
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Shivaiah Vaddypally; Sandeep K Kondaveeti; Michael J Zdilla |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-3-22 |
Journal Detail:
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Title: Inorganic chemistry Volume: - ISSN: 1520-510X ISO Abbreviation: - Publication Date: 2012 Mar |
Date Detail:
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Created Date: 2012-3-23 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 0366543 Medline TA: Inorg Chem Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Department of Chemistry, Temple University , Philadelphia, Pennsylvania 19122, United States. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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