| Suzuki-Miyaura coupling of heteroaryl boronic acids and vinyl chlorides. | |
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MedLine Citation:
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PMID: 22083103 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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A protocol for the Suzuki-Miyaura coupling of heteroaryl boronic acids and vinyl chlorides that minimizes protodeboronation is described. A combination of catalytic amounts of Pd(OAc)(2) and SPhos in conjunction with CsF in isopropanol effectively affords a variety of coupled products. Surprisingly, a dramatic temperature dependence in product selectivity was observed. |
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Authors:
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Ashish Thakur; Kainan Zhang; Janis Louie |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2011-11-14 |
Journal Detail:
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Title: Chemical communications (Cambridge, England) Volume: - ISSN: 1364-548X ISO Abbreviation: - Publication Date: 2011 Nov |
Date Detail:
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Created Date: 2011-11-15 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9610838 Medline TA: Chem Commun (Camb) Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, UT 84112, USA. louie@chem.utah.edu. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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