Document Detail


Surface modification of poly(oligoethylene oxide methacrylate) for resisting protein adsorption.
MedLine Citation:
PMID:  17141487     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
We prepare poly(2-methoxyethyl-, 2-(2-methoxyethoxy)ethyl-, 2-[2-(2-methoxyethoxy)ethoxy]ethyl methacrylate) (p(nEOMA), n=1, 2, and 3) brushed surfaces with varying the polymer density by surface initiated polymerization. The amount of bovine serum albumin (BSA) adsorbed on the surfaces is investigated. The mobility of the polymer chain in the polymer/water interfaces and the structure of adsorbed water on the surfaces are characterized by Electron Spin Resonance (ESR) and transmission-Fourier transform infrared (FT-IR) spectroscopy, respectively. This work reports the relationship between these surface properties and albumin adsorption. As a result, the surface having both a high molecular mobility and bulk-like water found to be very effective in preventing albumin adsorption.
Authors:
Tatsuya Tsukagoshi; Yukishige Kondo; Norio Yoshino
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Publication Detail:
Type:  Journal Article     Date:  2006-10-10
Journal Detail:
Title:  Colloids and surfaces. B, Biointerfaces     Volume:  54     ISSN:  0927-7765     ISO Abbreviation:  Colloids Surf B Biointerfaces     Publication Date:  2007 Jan 
Date Detail:
Created Date:  2007-01-02     Completed Date:  2007-03-07     Revised Date:  2009-10-16    
Medline Journal Info:
Nlm Unique ID:  9315133     Medline TA:  Colloids Surf B Biointerfaces     Country:  Netherlands    
Other Details:
Languages:  eng     Pagination:  94-100     Citation Subset:  IM    
Affiliation:
Department of Industrial Chemistry, Faculty of Engineering, Tokyo University of Science, 12-1 Ichigaya-Funagawara, Shinjuku-ku, Tokyo 162-0826, Japan.
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MeSH Terms
Descriptor/Qualifier:
Adsorption
Animals
Cattle
Electron Spin Resonance Spectroscopy
Methacrylates / chemistry*
Molecular Structure
Polyethylene Glycols / chemistry*
Serum Albumin, Bovine / chemistry*
Silicon Dioxide / chemistry
Spectroscopy, Fourier Transform Infrared
Surface Properties
Water / chemistry
Chemical
Reg. No./Substance:
0/Methacrylates; 0/Polyethylene Glycols; 0/Serum Albumin, Bovine; 0/poly(oligoethylene oxide methacrylate); 7631-86-9/Silicon Dioxide; 7732-18-5/Water

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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