| Sulfinyl-Mediated Stereoselective Overman Rearrangements and Diels-Alder Cycloadditions. | |
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MedLine Citation:
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PMID: 22630131 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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The Overman rearrangement of allylic sulfinyl trichloroacetimidates affords sulfinyl trichloroacetamides with high stereoselectivity and excellent yields. Bis-allylic substrates lead to amido 2-sulfinyl butadiene derivatives in excellent yields, with total chemo- and diastereoselectivity. The Diels-Alder cycloaddition of related dienes is controlled by the sulfoxide moiety. |
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Authors:
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Roberto Fernández de la Pradilla; Ignacio Colomer; Alma Viso |
Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-5-25 |
Journal Detail:
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Title: Organic letters Volume: - ISSN: 1523-7052 ISO Abbreviation: - Publication Date: 2012 May |
Date Detail:
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Created Date: 2012-5-28 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 100890393 Medline TA: Org Lett Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Instituto de Química Orgánica General, IQOG-CSIC , Juan de la Cierva 3, 28006 Madrid, Spain. |
Export Citation:
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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