Document Detail


Structural determination of subsidiary colors in commercial Food Green No. 3 (fast green FCF, FD & C Green No. 3).
MedLine Citation:
PMID:  11775354     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
HPLC analysis revealed that eight subsidiary colors existed in commercial Food Green No. 3 (fast green FCF, FD & C Green No. 3). Among them, four subsidiary colors C, F, G, and H were isolated by using preparative HPLC and their structures were determined by MS and NMR. They were the disodium salt of 2-[[4-[N-ethyl-N-(3- sulfophenylmethyl)amino]phenyl][4-[N-ethyl-N-(4- sulfophenylmethyl)amino]phenyl]methylio]-4-hydroxybenzenesulfonic acid (abbreviated as m,p-G-3), the sodium salt of 2-[[(4-N-ethylamino)phenyl][4-[N-ethyl-N-(3- sulfophenylmethyl)amino]-phenyl]methylio]-4-hydroxybenzenesulfonic acid [abbreviated as HSBA-(EA) (m-EBASA)], the sodium salt of 2-[[(4-N-diethylamino)phenyl][4-[N-ethyl-N-(3- sulfophenylmethyl)amino]phenyl]-methylio]-4-hydroxybenzenesulfonic acid [abbreviated as HSBA-(di-EA) (m-EBASA)], and the sodium salt of 2-[[4-[N-ethyl-N-(phenylmethyl)amino]phenyl][4-[N-ethyl-N-(3- sulfophenylmethyl)-amino]phenyl]methylio]-4-hydroxybenzenesulfonic acid [abbreviated as HSBA-(EBA)(m-EBASA)], respectively. HSBA-(di-EA) (m-EBASA) was a subsidiary color newly found in commercial Food Green No. 3.
Authors:
E Ngang; H Matsufuji; M Chino; Y Goda; M Toyoda; M Takeda
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Shokuhin eiseigaku zasshi. Journal of the Food Hygienic Society of Japan     Volume:  42     ISSN:  0015-6426     ISO Abbreviation:  Shokuhin Eiseigaku Zasshi     Publication Date:  2001 Oct 
Date Detail:
Created Date:  2002-01-01     Completed Date:  2002-02-08     Revised Date:  2006-11-15    
Medline Journal Info:
Nlm Unique ID:  0142214     Medline TA:  Shokuhin Eiseigaku Zasshi     Country:  Japan    
Other Details:
Languages:  eng     Pagination:  298-303     Citation Subset:  IM    
Affiliation:
College of Bioresource Sciences, Nihon University: 1866, Kameino, Fujisawa, Kanagawa, 252-8510, Japan.
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MeSH Terms
Descriptor/Qualifier:
Chromatography, High Pressure Liquid
Coal Tar
Food Coloring Agents / analysis,  chemistry*,  isolation & purification*
Lissamine Green Dyes / analysis,  chemistry*
Magnetic Resonance Spectroscopy
Mass Spectrometry
Chemical
Reg. No./Substance:
0/Food Coloring Agents; 0/Lissamine Green Dyes; 2353-45-9/Fast Green FCF; 8007-45-2/Coal Tar

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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