| Stereoselective Formation of Chiral Metallopeptides. | |
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MedLine Citation:
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PMID: 22555900 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Playing into our hands: The achiral bipyridine amino acid fluorenylmethyoxlcarbonyl 5-amino-3-oxapentanoic acid (Fmoc-O1PenBpy-OH) has been used for the solid-phase synthesis of metallopeptides. Circular dichroism, molecular modeling, and NMR spectroscopic studies show that the chirality of the resulting metal complexes in aqueous solution is determined, and can thus be controlled, by the stereochemistry of one proline residue in the loop between the two coordinating O1PenBpy residues. |
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Authors:
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Gustavo Rama; Ana Ardá; Jean-Didier Maréchal; Ilaria Gamba; Hitoshi Ishida; Jesús Jiménez-Barbero; M Eugenio Vázquez; Miguel Vázquez López |
Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-5-3 |
Journal Detail:
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Title: Chemistry (Weinheim an der Bergstrasse, Germany) Volume: - ISSN: 1521-3765 ISO Abbreviation: - Publication Date: 2012 May |
Date Detail:
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Created Date: 2012-5-4 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9513783 Medline TA: Chemistry Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Copyright Information:
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Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
Affiliation:
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Departamento de Química Inorgánica and, Centro Singular de Investigación en Química Biolóxica e, Materiais Moleculares (CIQUS), Universidade de Santiago de Compostela, 15782 Santiago de Compostela (Spain), Fax: (+34) 981-591-012. |
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