Document Detail


Stereochemical terminology and its discontents.
MedLine Citation:
PMID:  11835555     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
Scrutiny of the purported misuse of some current stereochemical terms shows that obsolescence and faulty syntax may be less of a problem than previously assumed. Furthermore, changes in stereochemical terminology over time are not always due to obsolescence or to novel developments in chemical technology; for example, technical developments played no role whatsoever in the semantic transmutations over time of the terms "diastereomer" and "pseudoasymmetry." Finally, definitions of many stereochemical terms acquire meaning only within a given context and therefore cannot always be easily formulated. A prime example is the definition of "chirality," the concept at the heart of stereochemistry and, not coincidentally, the name of the journal in which this essay appears in print.
Authors:
Kurt Mislow
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Chirality     Volume:  14     ISSN:  0899-0042     ISO Abbreviation:  Chirality     Publication Date:    2002 Feb-Mar
Date Detail:
Created Date:  2002-02-08     Completed Date:  2002-04-23     Revised Date:  2003-11-03    
Medline Journal Info:
Nlm Unique ID:  8914261     Medline TA:  Chirality     Country:  United States    
Other Details:
Languages:  eng     Pagination:  126-34     Citation Subset:  -    
Copyright Information:
Copyright 2002 Wiley-Liss, Inc.
Affiliation:
Department of Chemistry, Princeton University, Princeton, New Jersey 08544, USA. kmislow@princeton.edu
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