Document Detail


Steady and out-of-equilibrium phase diagram of a complex fluid at the nanolitre scale: combining microevaporation, confocal Raman imaging and small angle X-ray scattering.
MedLine Citation:
PMID:  23319166     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
We engineered specific microfluidic devices based on the pervaporation of water through a PDMS membrane, to formulate continuous and steady concentration gradients of a binary aqueous molecular mixture at the nanolitre scale. In the case of a model complex fluid (a triblock copolymer solution), we demonstrate that such a steady gradient crosses the phase diagram from pure water up to a succession of highly viscous mesophases. We then performed in situ spatially resolved measurements (confocal spectroscopy and small-angle X-ray scattering) to quantitatively measure the concentration profile and to determine the microstructure of the different textures. Within a single microfluidic channel, we thus screen quantitatively and continuously the phase diagram of a complex fluid. Beside, as such a gradient corresponds to an out-of-equilibrium regime, we also extract from the concentration measurement a precise estimate of the collective diffusion coefficient of the mixture as a function of the concentration. In the present case of the triblock copolymer, this transport coefficient features discontinuities at some phase boundaries, which have never been observed before.
Authors:
Laure Daubersies; Jacques Leng; Jean-Baptiste Salmon
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-1-14
Journal Detail:
Title:  Lab on a chip     Volume:  -     ISSN:  1473-0189     ISO Abbreviation:  Lab Chip     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-1-15     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101128948     Medline TA:  Lab Chip     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Univ. Bordeaux/CNRS/RHODIA, LOF, UMR 5258, 178, Avenue Schweitzer, F-33600 Pessac, France. jean-baptiste.salmon-exterieur@eu.rhodia.com.
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