| Spin-state control of thermal and photochemical Bergman cyclization. | |
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MedLine Citation:
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PMID: 23388700 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Thermal Bergman cyclization of Pt(ii) dialkynylporphyrins reveals a marked reduction in the cyclization temperature relative to the free base and Zn(ii) derivatives. In contrast, photogenerated (3)ππ* population produces no detectable Bergman photocyclization, suggesting that the photoreactivities of the related free base and Zn(ii) derivatives occurs via the (1)ππ* state. |
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Authors:
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Leigh J K Boerner; Maren Pink; Hyunsoo Park; Amanda Lesueur; Jeffrey M Zaleski |
Publication Detail:
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Type: JOURNAL ARTICLE Date: 2013-2-7 |
Journal Detail:
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Title: Chemical communications (Cambridge, England) Volume: - ISSN: 1364-548X ISO Abbreviation: Chem. Commun. (Camb.) Publication Date: 2013 Feb |
Date Detail:
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Created Date: 2013-2-7 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9610838 Medline TA: Chem Commun (Camb) Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Department of Chemistry, Indiana University, 800 East Kirkwood Avenue, Bloomington, Indiana, USA. zaleski@indiana.edu. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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