Document Detail


Spin interactions in mineral libethenite series: evolution of low-dimensional magnetism.
MedLine Citation:
PMID:  23032995     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Interesting magnetic properties and spin-exchange interactions along various possible pathways in the half-integral spin quantum magnetic tetramer system: A(2)PO(4)OH (A=Co, Cu) are investigated. Interplay of structural distortion and the magnetic properties with the evolution of localized band structure explain the gradual transition from a three-dimensional antiferromagnet to a low-dimensional frustrated magnetic system along the series. A detailed study of the exchange mechanism in this system explores various possibilities of complex magnetic interaction. The electronic structure of this series, studied with the help of different appropriate density functional approaches such as Nth order muffin-tin orbital (NMTO) and plane-wave pseudopotential calculations incorporating onsite Coulomb repulsion (U), identifies the underlying magnetic exchange mechanism of this series. Thereafter a generalized minimal model spin-Hamiltonian is constructed for the low-dimensional system. Solution of this model Hamiltonian within first-order perturbation theory results in the evaluation of spin-gap in the spin-tetramer system. In addition, the effects of size confinement and volume reduction on the relevant exchange integrals and spin-gap of the low-dimensional system are also discussed.
Authors:
Debjani Karmakar; J V Yakhmi
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-10-03
Journal Detail:
Title:  Journal of physics. Condensed matter : an Institute of Physics journal     Volume:  24     ISSN:  1361-648X     ISO Abbreviation:  J Phys Condens Matter     Publication Date:  2012 Oct 
Date Detail:
Created Date:  2012-10-3     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101165248     Medline TA:  J Phys Condens Matter     Country:  -    
Other Details:
Languages:  ENG     Pagination:  436003     Citation Subset:  -    
Affiliation:
Technical Physics Division, Bhabha Atomic Research Center, Mumbai 400085, India.
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