Document Detail


Spin and orbital magnetic moment anisotropies of monodispersed bis(phthalocyaninato)terbium on a copper surface.
MedLine Citation:
PMID:  20698538     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
The magnetic properties of isolated TbPc(2) molecules supported on a Cu(100) surface are investigated by X-ray magnetic circular dichroism at 8 K in magnetic fields up to 5 T. The crystal field and magnetic properties of single molecules are found to be robust upon adsorption on a metal substrate. The Tb magnetic moment has Ising-like magnetization; XMCD spectra combined with multiplet calculations show that the saturation orbital and spin magnetic moment values reach 3 and 6 mu(B), respectively.
Authors:
Sebastian Stepanow; Jan Honolka; Pietro Gambardella; Lucia Vitali; Nasiba Abdurakhmanova; Tzu-Chun Tseng; Stephan Rauschenbach; Steven L Tait; Violetta Sessi; Svetlana Klyatskaya; Mario Ruben; Klaus Kern
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  Journal of the American Chemical Society     Volume:  132     ISSN:  1520-5126     ISO Abbreviation:  J. Am. Chem. Soc.     Publication Date:  2010 Sep 
Date Detail:
Created Date:  2010-08-25     Completed Date:  2010-12-08     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  7503056     Medline TA:  J Am Chem Soc     Country:  United States    
Other Details:
Languages:  eng     Pagination:  11900-1     Citation Subset:  IM    
Affiliation:
Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, D-70569 Stuttgart, Germany. s.stepanow@fkf.mpg.de
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MeSH Terms
Descriptor/Qualifier:
Adsorption
Anisotropy
Circular Dichroism
Coordination Complexes / chemistry*
Copper / chemistry*
Magnetics*
Particle Size
Surface Properties
Chemical
Reg. No./Substance:
0/Coordination Complexes; 7440-50-8/Copper

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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