Document Detail

Spectrophotometric determination of gold(iii) with p-dimethylaminobenzilidenerhodanine in hydrochloric acid-ethanol medium.
MedLine Citation:
PMID:  18961736     Owner:  NLM     Status:  In-Data-Review    
The reaction between gold(III) and p-dimethylaminobenzilidenerhodanine in hydrochloric acid medium containing 20% v/v ethanol has been studied spectrophotometrically. It has been established that the process is very complicated: gold(III) is reduced to gold(I) which reacts with unchanged reagent. The value of the equilibrium constant is 2.56 +/- 0.45. Conditions are proposed for the determination of 2-8 mug of gold in 25 ml, with a standard deviation of 0.04 mug 25 ml .
R Borissova
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Talanta     Volume:  22     ISSN:  0039-9140     ISO Abbreviation:  Talanta     Publication Date:    1975 October - November
Date Detail:
Created Date:  2008-10-30     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  2984816R     Medline TA:  Talanta     Country:  England    
Other Details:
Languages:  eng     Pagination:  797-802     Citation Subset:  -    
Department of Analytical Chemistry, Higher Institute of Chemical Technology, Sofia-56, Bulgaria.
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