Document Detail


Spectral Response to Protonation of 4-(4-(4-(Didodecylamino)phenylazo)phenyl)butyric Acid in Its Langmuir-Blodgett Monolayer.
MedLine Citation:
PMID:  10767146     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
4-(4-(4-(Didodecylamino)phenylazo)phenyl)butyric acid is synthesized, and its Langmuir-Blodgett (LB) monolayer is successfully fabricated. The drastic changes in electronic spectra of this compound are found in acidic solution and in LB monolayer upon exposure to HCl vapor (mainly the decrease in absorption at 416 nm and great increase at 540 nm). The UV-visible and infrared spectra reveal a mechanism of protonation to either azo group or amino group. This phenomenon has been suggested to have its prospective application in fundamental interfacial materials for pH sensors. Copyright 2000 Academic Press.
Authors:
Zhao; Akiyama; Liu; Nakanishi
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Publication Detail:
Type:  JOURNAL ARTICLE    
Journal Detail:
Title:  Journal of colloid and interface science     Volume:  225     ISSN:  1095-7103     ISO Abbreviation:  J Colloid Interface Sci     Publication Date:  2000 May 
Date Detail:
Created Date:  2000-04-17     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0043125     Medline TA:  J Colloid Interface Sci     Country:  -    
Other Details:
Languages:  ENG     Pagination:  62-68     Citation Subset:  -    
Affiliation:
National Institute of Materials and Chemical Research, 1-1 Higashi, Tsukuba, Ibaraki, 305-8565, Japan
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