Document Detail


Spatially resolved NMR thermometry of an operating fixed-bed catalytic reactor.
MedLine Citation:
PMID:  18642909     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
An MRI-based approach for the thermometry of an operating packed-bed catalytic reactor was implemented. It was employed for the spatially resolved NMR thermometry of the bed of Pd/gamma-Al2O3 catalyst beads in the course of propylene hydrogenation reaction. This was achieved by detecting the spatially resolved axial 1D profiles of the 27Al NMR signal intensity of Al2O3 in the course of the reaction. The experimental results demonstrate a clear correlation between the 27Al NMR signal intensity and the catalyst temperature measured with a thermocouple (25-250 degrees C), and reveal the existence of pronounced temperature gradients along the catalyst bed.
Authors:
Igor V Koptyug; Alexey V Khomichev; Anna A Lysova; Renad Z Sagdeev
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Publication Detail:
Type:  Journal Article     Date:  2008-07-22
Journal Detail:
Title:  Journal of the American Chemical Society     Volume:  130     ISSN:  1520-5126     ISO Abbreviation:  J. Am. Chem. Soc.     Publication Date:  2008 Aug 
Date Detail:
Created Date:  2008-08-06     Completed Date:  2008-10-06     Revised Date:  2009-01-08    
Medline Journal Info:
Nlm Unique ID:  7503056     Medline TA:  J Am Chem Soc     Country:  United States    
Other Details:
Languages:  eng     Pagination:  10452-3     Citation Subset:  -    
Affiliation:
International Tomography Center, SB RAS, Novosibirsk, Russia. koptyug@tomo.nsc.ru
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