Document Detail


Sorption Characteristics of Caffeine onto Untreated Polyurethane Foam: Application to Its Determination in Human Plasma.
MedLine Citation:
PMID:  22076341     Owner:  NLM     Status:  In-Data-Review    
Abstract/OtherAbstract:
In the present paper, the sorption properties of caffeine (CAF) onto polyether type polyurethane foam (PUF) as solid phase sorbent were investigated with UV determination at 274.3 nm. Batch and column methods were used to optimize chemical, flow, kinetic and isothermal conditions for preconcentration of CAF. Results indicated quantitative sorption of CAF at pH 8 and 30 min shaking time. The maximum sorption capacity was found to be 4.1 mg g(-1). Column preconcentration was recommended at a flow rate of 1.5 mL min(-1) and desorption with 4 mL from 0.15 mol L(-1) hydrochloric acid. The procedure provided a linear analytical range of 0.05 - 30 mg L(-1). The detection and quantification limits are 0.016 and 0.047 mg L(-1), respectively. The procedure was applied to determination of CAF in spiked human plasma. The obtained recoveries were 98 - 101% and RSD values were from 0.05 to 9.5%.
Authors:
Samy M Abdel Azeem; Samah Ali; Mohamed F El-Shahat
Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Analytical sciences : the international journal of the Japan Society for Analytical Chemistry     Volume:  27     ISSN:  1348-2246     ISO Abbreviation:  Anal Sci     Publication Date:  2011  
Date Detail:
Created Date:  2011-11-14     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  8511078     Medline TA:  Anal Sci     Country:  Japan    
Other Details:
Languages:  eng     Pagination:  1133     Citation Subset:  IM    
Affiliation:
Chemistry Department, Faculty of Science, Fayoum University.
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