Document Detail


Sonochemical effects on free phenolic acids under ultrasound treatment in a model system.
MedLine Citation:
PMID:  23339884     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Sonochemical effects on seven free phenolic acids under ultrasound treatment in a model system have been investigated. The degradation products have also been tentatively identified by FTIR and HPLC-UV-ESIMS. Five phenolic acids (protocatechuic acid, p-hydroxybenzoic acid, vanillic acid, p-coumaric acid, and ferulic acid) proved to be stable, while two others (caffeic acid and sinapic acid) were degraded under ultrasound treatment. The nature of the solvent and the temperature has been identified as important factors in determining the degradation reaction. Liquid height, ultrasonic intensity, and duty cycle of the ultrasound exposure affected only the degradation rate and did not change the nature of the degradation. The degradation rates of caffeic acid and sinapic acid decreased with increasing temperature. The degradation kinetics of these two acids under ultrasound conformed to zeroth-order reactions at -5 to 25°C. Both decomposition and polymerization reactions occurred when caffeic acid and sinapic acid were subjected to ultrasound. Degradation products, such as the corresponding decarboxylation products and their dimers, have been tentatively identified.
Authors:
Liping Qiao; Xingqian Ye; Yujing Sun; Jieqi Ying; Yan Shen; Jianchu Chen
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-1-5
Journal Detail:
Title:  Ultrasonics sonochemistry     Volume:  -     ISSN:  1873-2828     ISO Abbreviation:  Ultrason Sonochem     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-1-23     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9433356     Medline TA:  Ultrason Sonochem     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Crown Copyright © 2013. Published by Elsevier B.V. All rights reserved.
Affiliation:
Department of Food Science and Nutrition, School of Biosystems, Engineering and Food Science, Zhejiang University, Hangzhou 310058, PR China.
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