Document Detail


Some characteristics of beta-naphthyl oligophosphates as allosteric effectors of human hemoglobin.
MedLine Citation:
PMID:  7106359     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
1. Fluorescent organic phosphates. beta-naphthyl oligophosphates, were found to interact with human hemoglobin, and to lower the oxygen affinity. The magnitude of the allosteric effect depended on the number of phosphoric groups in each compound. 2. In analogy with inositol hexaphosphate (IHP). beta-naphthyl tetraphosphate (beta-NapP4) was found to interact with oxyhemoglobin. Therefore, the spectral changes in oxyhemoglobin and carboxyhemoglobin induced by beta-NapP4 and IHP were compared. 3. The extent of spectral changes in oxyhemoglobin induced by beta-NapP4 was smaller than that induced by IHP, whereas the extent of spectral changes in carboxyhemoglobin induced by beta-NapP4 was about twice that by IHP. 4. These results indicate that there is a structural difference between oxyhemoglobin and carboxyhemoglobin.
Authors:
K Horiuchi
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  The International journal of biochemistry     Volume:  14     ISSN:  0020-711X     ISO Abbreviation:  Int. J. Biochem.     Publication Date:  1982  
Date Detail:
Created Date:  1982-10-29     Completed Date:  1982-10-29     Revised Date:  2008-11-21    
Medline Journal Info:
Nlm Unique ID:  0250365     Medline TA:  Int J Biochem     Country:  ENGLAND    
Other Details:
Languages:  eng     Pagination:  601-8     Citation Subset:  IM    
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MeSH Terms
Descriptor/Qualifier:
Allosteric Regulation / drug effects
Carboxyhemoglobin / metabolism
Chemical Phenomena
Chemistry
Humans
Naphthols / blood,  pharmacology*
Organophosphorus Compounds / blood,  pharmacology*
Oxyhemoglobins / metabolism*
Phytic Acid / pharmacology
Protein Binding
Spectrophotometry
Stereoisomerism
Structure-Activity Relationship
Chemical
Reg. No./Substance:
0/Naphthols; 0/Organophosphorus Compounds; 0/Oxyhemoglobins; 83-86-3/Phytic Acid; 9061-29-4/Carboxyhemoglobin

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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