Document Detail

Solvent-modulated metamagnetism in an Fe(ii) system exhibiting a two-step field-induced magnetic transition.
MedLine Citation:
PMID:  22531961     Owner:  NLM     Status:  In-Data-Review    
A one-dimensional iron(ii) coordination polymer, [Fe(3)(hpdc)(2)(H(2)O)(6)]·2H(2)O (H(3)hpdc = 2-hydroxypyrimidine-4,6-dicarboxylic acid) has been synthesized and characterized. The compound exhibits field-induced two-step magnetic phase transitions and a coexistence of spin-canting and metamagnetism, and undergoes a structural transformation from single-crystalline to amorphous state upon dehydration, accompanied by significantly enhanced spontaneous magnetization and critical temperature.
Chun-Ding Zhou; Chao Chen; Li-Xuan Cai; Jie Zhang
Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Dalton transactions (Cambridge, England : 2003)     Volume:  41     ISSN:  1477-9234     ISO Abbreviation:  Dalton Trans     Publication Date:  2012 May 
Date Detail:
Created Date:  2012-04-25     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101176026     Medline TA:  Dalton Trans     Country:  England    
Other Details:
Languages:  eng     Pagination:  5912-8     Citation Subset:  IM    
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China.
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