Document Detail

Solid-state P-31 NMR study of the formation of hydroxyapatite in the presence of glutaric acid.
MedLine Citation:
PMID:  18306172     Owner:  NLM     Status:  MEDLINE    
We demonstrate that glutaric acid can be used to prepare nanorods of hydroxyapatite under hydrothermal condition at 100 degrees C with a Ca(2+):glutaric acid molar ratio of 1:4. Frequency-switched Lee-Goldburg irradiation is employed to obtain high-resolution (31)P{(1)H} correlation spectra of the reaction mixture at two different reaction periods, from which it is shown that octacalcium phosphate is the precursor phase of the final hydroxyapatite product. In addition, the spectra show that a substantial amount of water molecules is trapped between the glutaric acid and the hydroxyapatite surface, indicating that water molecules may play a prominent role in the noncovalent interaction of the glutaric acid and the HAp surface.
Yao-Hung Tseng; Yun Mou; Peng-Huan Chen; Tim W T Tsai; Cheng-I Hsieh; Chung-Yuan Mou; Jerry C C Chan
Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  Magnetic resonance in chemistry : MRC     Volume:  46     ISSN:  1097-458X     ISO Abbreviation:  Magn Reson Chem     Publication Date:  2008 Apr 
Date Detail:
Created Date:  2008-03-04     Completed Date:  2008-04-16     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9882600     Medline TA:  Magn Reson Chem     Country:  England    
Other Details:
Languages:  eng     Pagination:  330-4     Citation Subset:  IM    
Copyright Information:
Copyright (c) 2008 John Wiley & Sons, Ltd.
Department of Chemistry, National Taiwan University, No. 1, Section 4, Roosevelt Road, Taipei, Taiwan.
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MeSH Terms
Durapatite / chemical synthesis*,  chemistry*
Glutarates / chemistry*
Magnetic Resonance Spectroscopy / methods*,  standards
Microscopy, Electron, Scanning
Particle Size
Phosphorus Isotopes
Reference Standards
X-Ray Diffraction
Reg. No./Substance:
0/Glutarates; 0/Phosphorus Isotopes; 110-94-1/glutaric acid; 1306-06-5/Durapatite

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