Document Detail

Size controlled mechanochemical synthesis of ZrSi(2).
MedLine Citation:
PMID:  23230567     Owner:  NLM     Status:  Publisher    
Mechanochemical metathesis reactions were utilized to synthesize nanocrystalline ZrSi(2) ranging from 9-30 nm in size. Size was controlled through dilution with CaCl(2). A linear relationship was found between diluent concentration and crystallite size. Unlike typical self-propagating metathesis reactions, this reaction did not self-propagate, requiring the input of mechanical energy.
David Restrepo; Sandra M Hick; Carolin Griebel; Juan Alarcón; Kyle Giesler; Yan Chen; Nina Orlovskaya; Richard G Blair
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-12-11
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2012 Dec 
Date Detail:
Created Date:  2012-12-11     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Department of Chemistry, University of Central Florida, Orlando, FL 32816, USA.
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