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Single-molecule magnet based on a C-type polyoxomolybdate with an S = 11 ground state: [Fe(5)CoMo(22)As(2)O(85)(H(2)O)](15-).
MedLine Citation:
PMID:  23135131     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
A C-type polyoxomolybdate containing a mixed-transition metal cluster Fe(5)Co has been prepared as an ammonium salt, (NH(4))(15)[Fe(5)CoMo(22)As(2)O(85)(H(2)O)]·15H(2)O (). Interestingly, the magnetism measurements show that the compound exhibits not only an overall ferromagnetic cluster with a large spin ground state of S = 11 but also the behavior of single-molecule magnets.
Authors:
Yanzhong Zhen; Bin Liu; Lili Li; Danjun Wang; Ying Ma; Huaiming Hu; Shengli Gao; Ganglin Xue
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-11-8
Journal Detail:
Title:  Dalton transactions (Cambridge, England : 2003)     Volume:  -     ISSN:  1477-9234     ISO Abbreviation:  Dalton Trans     Publication Date:  2012 Nov 
Date Detail:
Created Date:  2012-11-8     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101176026     Medline TA:  Dalton Trans     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), Department of Chemistry, Northwest University, Xi'an, 710069, China. xglin707@163.com.
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