| Significant influence of Zn on activation of the C-H bonds of small alkanes by Brønsted acid sites of zeolite. | |
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MedLine Citation:
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PMID: 18972491 Owner: NLM Status: PubMed-not-MEDLINE |
Abstract/OtherAbstract:
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Herein, we analyze earlier obtained and new data about peculiarities of the H/D hydrogen exchange of small C(1)-n-C(4) alkanes on Zn-modified high-silica zeolites ZSM-5 and BEA in comparison with the exchange for corresponding purely acidic forms of these zeolites. This allows us to identify an evident promoting effect of Zn on the activation of C-H bonds of alkanes by zeolite Brønsted sites. The effect of Zn is demonstrated by observing the regioselectivity of the H/D exchange for propane and n-butane as well as by the increase in the rate and a decrease in the apparent activation energy of the exchange for all C(1)-n-C(4) alkanes upon modification of zeolites with Zn. The influence of Zn on alkane activation has been rationalized by dissociative adsorption of alkanes on Zn oxide species inside zeolite pores, which precedes the interaction of alkane with Brønsted acid sites. |
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Authors:
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Alexander G Stepanov; Sergei S Arzumanov; Anton A Gabrienko; Valentin N Parmon; Irina I Ivanova; Dieter Freude |
Publication Detail:
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Type: Journal Article |
Journal Detail:
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Title: Chemphyschem : a European journal of chemical physics and physical chemistry Volume: 9 ISSN: 1439-7641 ISO Abbreviation: Chemphyschem Publication Date: 2008 Dec |
Date Detail:
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Created Date: 2008-12-02 Completed Date: 2009-01-16 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 100954211 Medline TA: Chemphyschem Country: Germany |
Other Details:
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Languages: eng Pagination: 2559-63 Citation Subset: - |
Affiliation:
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Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Prospekt Akademika Lavrentieva 5, Novosibirsk 630090, Russia. stepanov@catalysis.ru |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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