Document Detail


Serendipitous anion-templated self-assembly of a sandwich-like Ag(20)S(10) macrocycle-based high-nuclearity luminescent nanocluster.
MedLine Citation:
PMID:  23208528     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The first macrocycle-based high-nuclearity nanocluster [Ag(20)(S(t)Bu)(10)(CF(3)COO)(2)](8+) in complex , with a sandwich-like structure constructed by bilevel inversion Ag(5)S(5) pentagrams and an interlayer Ag(10) ring, has been obtained. Structure analysis indicates that Cl(-) acts as an anion template to direct the formation of . In addition, the photoluminescent property of complex is also investigated.
Authors:
Kun Zhou; Xin-Long Wang; Chao Qin; Hai-Ning Wang; Guang-Sheng Yang; Yan-Qing Jiao; Peng Huang; Kui-Zhan Shao; Zhong-Min Su
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-12-3
Journal Detail:
Title:  Dalton transactions (Cambridge, England : 2003)     Volume:  -     ISSN:  1477-9234     ISO Abbreviation:  Dalton Trans     Publication Date:  2012 Dec 
Date Detail:
Created Date:  2012-12-4     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101176026     Medline TA:  Dalton Trans     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Institute of Functional Material Chemistry, Key Lab of Polyoxometalate, Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024 Jilin, People's Republic of China. zmsu@nenu.edu.cn qinc703@nenu.edu.cn.
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