Document Detail


Separation of amino acid phenylthiohydantoin derivatives by high-pressure liquid chromatography.
MedLine Citation:
PMID:  3728965     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Separation of the phenylthiohydantoin (PTH) derivatives of all 20 common amino acids is accomplished in approximately 11 min with excellent resolution by using high-pressure liquid chromatography. The chromatography is achieved at 50 degrees C on an Altex reversed-phase PTH-C18 column in an ammonium acetate-buffered acetonitrile, pH 4.5, mobile phase. Simple isocratic and linear gradient steps are used. Retention times for the various PTH-amino acids are very reproducible. Because the baseline is flat and free of background noise, PTH-amino acids can be detected in the low picomole range. The simplicity of this chromatographic system allows it to be easily automated.
Authors:
J L Meuth; J L Fox
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Analytical biochemistry     Volume:  154     ISSN:  0003-2697     ISO Abbreviation:  Anal. Biochem.     Publication Date:  1986 May 
Date Detail:
Created Date:  1986-07-25     Completed Date:  1986-07-25     Revised Date:  2000-12-18    
Medline Journal Info:
Nlm Unique ID:  0370535     Medline TA:  Anal Biochem     Country:  UNITED STATES    
Other Details:
Languages:  eng     Pagination:  478-84     Citation Subset:  IM    
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MeSH Terms
Descriptor/Qualifier:
Amino Acid Sequence
Amino Acids / isolation & purification*
Chromatography, High Pressure Liquid
Hydantoins / isolation & purification*
Hydrogen-Ion Concentration
Microchemistry
Phenylthiohydantoin / analogs & derivatives,  isolation & purification*
Chemical
Reg. No./Substance:
0/Amino Acids; 0/Hydantoins; 2010-15-3/Phenylthiohydantoin

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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