Document Detail


Sensitive fluorescence detection of polyphosphate in polyacrylamide gels using 4',6-diamidino-2-phenylindol.
MedLine Citation:
PMID:  17847128     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
PAGE is commonly used to identify and resolve inorganic polyphosphates (polyP). We now report highly sensitive and specific staining methods for polyP in polyacrylamide gels based on the fluorescent dye, 4',6-diamidino-2-phenylindol (DAPI). DAPI bound to polyP in gels fluoresced yellow while DAPI bound to nucleic acids or glycosaminoglycans fluoresced blue. Inclusion of EDTA prevented staining of glycosaminoglycans by DAPI. We also identified conditions under which DAPI that was bound to polyP (but not nucleic acids or other anionic polymers) rapidly photobleached. This allowed us to develop an even more sensitive and specific negative staining method that distinguishes polyP from nucleic acids and glycosaminoglycans. The lower LOD using DAPI negative staining was 4 pmol (0.3 ng) phosphate per band, compared to conventional toluidine blue staining with a lower LOD of 250 pmol per band.
Authors:
Stephanie A Smith; James H Morrissey
Related Documents :
18968108 - Ftir spectroscopy studies of nucleic acid damage.
14627838 - Real-time monitoring of nucleic acid ligation in homogenous solutions using molecular b...
11714598 - Novel spermine-amino acid conjugates and basic tripeptides enhance cleavage of the hair...
2101888 - Watersoluble synthetic nucleic acid analogs--polyethyleneimine derivatives containing n...
8368 - Purification and characterisation of four polypeptides with neurotoxic activity from co...
3097228 - Nascent high density lipoproteins from liver perfusates of orotic acid-fed rats.
Publication Detail:
Type:  Journal Article; Research Support, N.I.H., Extramural; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  Electrophoresis     Volume:  28     ISSN:  0173-0835     ISO Abbreviation:  Electrophoresis     Publication Date:  2007 Oct 
Date Detail:
Created Date:  2007-10-08     Completed Date:  2008-02-06     Revised Date:  2010-08-24    
Medline Journal Info:
Nlm Unique ID:  8204476     Medline TA:  Electrophoresis     Country:  Germany    
Other Details:
Languages:  eng     Pagination:  3461-5     Citation Subset:  IM    
Affiliation:
Department of Internal Medicine, College of Medicine, University of Illinois at Urbana-Champaign, 506 S. Mathews, Urbana, IL 61801, USA. sasmith6@uiuc.edu
Export Citation:
APA/MLA Format     Download EndNote     Download BibTex
MeSH Terms
Descriptor/Qualifier:
Edetic Acid / chemistry
Electrophoresis, Polyacrylamide Gel / methods*
Fluorescent Dyes / chemistry*
Glycosaminoglycans / chemistry
Indoles / chemistry*
Nucleic Acids / chemistry
Polyphosphates / analysis*,  chemistry*
Sensitivity and Specificity
Spectrometry, Fluorescence
Staining and Labeling / methods*
Grant Support
ID/Acronym/Agency:
HL 47014/HL/NHLBI NIH HHS; R01 HL047014-15/HL/NHLBI NIH HHS
Chemical
Reg. No./Substance:
0/Fluorescent Dyes; 0/Glycosaminoglycans; 0/Indoles; 0/Nucleic Acids; 0/Polyphosphates; 47165-04-8/DAPI; 60-00-4/Edetic Acid

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


Previous Document:  Effects of water deprivation on the pharmacokinetics of theophylline and one of its metabolites, 1,3...
Next Document:  A fast CE method for the achiral separation of methadone and its major metabolites, 2-ethylidene-1,5...