| Self-oscillating polymer fueled by organic acid. | |
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MedLine Citation:
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PMID: 18588335 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
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Here we report the biomimetic polymer that causes self-oscillation driven by the addition of biorelated organic acid. We constructed the built-in system where all of the substrates of the BZ reaction other than biorelated organic substrates were incorporated into the polymer chain. The quarternary copolymer, which includes both of the pH-control and oxidant-supplying sites in the poly(N-isopropylacrylamide-co-Ru(bpy)3) chain was synthesized. By using the polymer, we first succeeded in causing the self-oscillation of the polymer only in the coexistence of organic acid. |
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Authors:
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Yusuke Hara; Ryo Yoshida |
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Publication Detail:
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Type: Letter; Research Support, Non-U.S. Gov't Date: 2008-06-28 |
Journal Detail:
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Title: The journal of physical chemistry. B Volume: 112 ISSN: 1520-6106 ISO Abbreviation: J Phys Chem B Publication Date: 2008 Jul |
Date Detail:
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Created Date: 2008-07-18 Completed Date: 2008-11-13 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 101157530 Medline TA: J Phys Chem B Country: United States |
Other Details:
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Languages: eng Pagination: 8427-9 Citation Subset: IM |
Export Citation:
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| MeSH Terms | |
Descriptor/Qualifier:
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Acrylamides
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chemistry* Biocompatible Materials / chemical synthesis* Hydrogen-Ion Concentration Malonates / chemistry* Molecular Structure Organometallic Compounds / chemical synthesis* Polymers / chemistry* Ruthenium / chemistry* Solubility |
| Chemical | |
Reg. No./Substance:
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0/Acrylamides; 0/Biocompatible Materials; 0/Malonates; 0/Organometallic Compounds; 0/Polymers; 0/poly(N-isopropylacrylamide); 141-82-2/malonic acid; 7440-18-8/Ruthenium |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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