Document Detail


Self-interaction correction and the optimized effective potential.
MedLine Citation:
PMID:  18624473     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Self-interaction is one of the most substantial problems in present-day density functional theory. A widely used approach to overcome this problem is the self-interaction correction proposed by Perdew and Zunger. However, the thus given functional not only depends on the orbitals explicitly but is also variant under unitary transformation of the orbitals. In this manuscript, we present a generalized version of the optimized effective potential equation which is able to deal with both problems in one go. Calculations for molecules exemplify the approach.
Authors:
T Körzdörfer; S Kümmel; M Mundt
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  The Journal of chemical physics     Volume:  129     ISSN:  1089-7690     ISO Abbreviation:  J Chem Phys     Publication Date:  2008 Jul 
Date Detail:
Created Date:  2008-07-15     Completed Date:  2008-09-26     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0375360     Medline TA:  J Chem Phys     Country:  United States    
Other Details:
Languages:  eng     Pagination:  014110     Citation Subset:  IM    
Affiliation:
Physics Institute, University of Bayreuth, D-95440 Bayreuth, Germany. thomas.koerzdoerfer@uni-bayreuth.de
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MeSH Terms
Descriptor/Qualifier:
Artifacts
Electrons
Quantum Theory*

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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