Document Detail


Self-decarboxylation of trichloroacetic acid redox catalyzed by trichloroacetate ions in acetonitrile solutions.
MedLine Citation:
PMID:  23165440     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
In mixtures of trichloroacetate ion and trichloroacetic acid in acetonitrile, trichloromethyl radicals are produced as a result of the redox reaction between the acid and its conjugate base. The reaction follows a loop mechanism in which the trichloroacetic acid is slowly consumed by proton reduction while the trichloroacetate ion is oxidized like in an electrochemical Kolbe reaction. The hydroquinone-trichloroacetate complex was a good sensor of this unexpected self-decarboxylation redox reaction.
Authors:
Drochss P Valencia; Pablo D Astudillo; Annia Galano; Felipe J González
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-11-19
Journal Detail:
Title:  Organic & biomolecular chemistry     Volume:  -     ISSN:  1477-0539     ISO Abbreviation:  Org. Biomol. Chem.     Publication Date:  2012 Nov 
Date Detail:
Created Date:  2012-11-20     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101154995     Medline TA:  Org Biomol Chem     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Departamento de Química del Centro de Investigación y de Estudios Avanzados del I.P.N., Av. IPN 2508, Col. San Pedro Zacatenco, 07360, Distrito Federal, Mexico. fgonzale@cinvestav.mx.
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